Zirconium alloy
Zirconium alloy
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  • Zirconium alloy
  • Zirconium alloy
Zirconium alloy

Zirconium alloys can be classified into two major categories—nuclear-grade zirconium alloys and industrial-grade zirconium alloys—based on their application fields and compositional systems. Among these, nuclear-grade zirconium alloys are the most representative category. The composition and properties of each grade are tailored to specific applications. The following is a list of mainstream grades and their classifications:

Category

Alloy system

Grade

Core ingredient features

Key Performance Advantages

Applicable scenarios

Nuclear-grade zirconium alloy

Zirconium-tin (Zr-Sn) system

Zr-2

Contains Sn, Fe, Cr, Ni

Excellent resistance to corrosion on the water-facing side.

Boiling Water Reactor (BWR) fuel cladding and component grids

Nuclear-grade zirconium alloy

Zirconium-tin (Zr-Sn) system

Zr-4

Based on Zr-2, remove Ni and adjust the Fe/Cr ratio.

Stronger resistance to hydrogen embrittlement

Pressurized Water Reactor (PWR) fuel cladding (most widely used)

Nuclear-grade zirconium alloy

Zirconium-tin (Zr-Sn) system

Zr-3

Contains Sn, Fe, Cr

Corrosion resistance is between that of Zr-2 and Zr-4.

Boiling Water Reactor (BWR) components

Nuclear-grade zirconium alloy

Zirconium-Niobium (Zr-Nb) system

Zr-1Nb

Contains 1% Nb

Good plasticity

Nuclear reactor structural components

Nuclear-grade zirconium alloy

Zirconium-Niobium (Zr-Nb) system

Zr-2.5Nb

Contains 2.5% Nb

High strength and resistant to high-pressure water corrosion

Heavy-water reactor (CANDU) pressure tubes and fuel channels

Nuclear-grade zirconium alloy

Zirconium-Niobium (Zr-Nb) system

M5®

Contains Nb and O; does not contain Sn, Fe, or Cr.

Excellent radiation-resistant growth and corrosion performance.

Advanced Fuel Cladding for Pressurized Water Reactors (PWRs)

Nuclear-grade zirconium alloy

Zirconium-Niobium (Zr-Nb) system

E110

Contains 1% Nb

Stable overall performance

Russian pressurized water reactor fuel cladding and structural components

Nuclear-grade zirconium alloy

Zirconium-Niobium (Zr-Nb) system

E635

Improved Zirconium-Niobium Formula

Superior overall performance compared to E110.

Advanced nuclear reactor components from Russia

Industrial zirconium alloy

Pure zirconium-based

Zr-702

Zr ≥ 99.2% (pure zirconium alloy)

Excellent corrosion resistance

Chemical equipment, heat exchangers, and valves (widely used in industrial applications)

Industrial zirconium alloy

Zirconium-tin system

Zr-704

Contains small amounts of Sn and Fe.

Slightly higher strength than Zr-702, with corrosion resistance comparable to it.

Components with a certain level of corrosion resistance are required.

Industrial zirconium alloy

Zirconium-niobium system

Zr-705

Contains 2.5% Nb

High strength, good ductility, and excellent weldability.

Marine engineering, high-pressure chemical equipment, aerospace structural components

Industrial zirconium alloy

Zirconium-titanium series

Zr-Ti alloy

Contains a small amount of Ti

High strength at high temperatures and good machinability.

Medium- and high-temperature corrosion-resistant components

Industrial zirconium alloy

Zirconium-copper system

Zr-Cu alloy

Contains trace amounts of Cu

Good casting performance and excellent wear resistance.

Casting corrosion-resistant parts

Zirconium alloy for special purposes

Zirconium-hafnium system

Zr-Hf alloy

Containing hafnium (Hf)

Tunable neutron absorption performance

Specific structural components of a nuclear reactor

Zirconium alloy for special purposes

Zirconium-rare earth series

Zirconium-rare earth alloy

Add rare-earth elements such as Ce and Y.

Good high-temperature oxidation resistance and high strength.

Aerospace high-temperature components

 

Core Grade Summary
Nuclear-grade zirconium alloys Zr-4, Zr-2.5Nb, M5®, and E110—fuel cladding and pressure tubes for nuclear reactors
Industrial zirconium alloys Zr-702, Zr-705, and Zr-704—corrosion-resistant equipment for the chemical industry and marine engineering.

Among them, Zr-702 (industrial) and Zr-4 (nuclear-grade) are currently the two zirconium alloy grades with the largest global application volumes.

 

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